The mechanochemistry of lanthanum dihydride (LaH2) with hydrogen (H2) using the ball-mill process and the effect of oxidation on the resulting products

Authors

• Andika Widya Pramono
• Satrio Herbirowo
• Agung Imaduddin
• Iwan Dwi Antoro
• Heri Nugraha
• Hendrik -
• Anung Syampurwadi
• Ines Hayatun Nufus
• Nihayatul Umna
• Silvia Farah Diba
• Fina Fitratun Amaliyah

Publication Date

2024

Abstract

The complex behavior of LaH2 during ball milling was investigated in this study, with its mechanical, chemical, and morphological changes explored. The relationship between milling time and hydrogen pressure reduction was uncovered through detailed experiments, reflecting the dynamic nature of the process. A transient yet significant event was observed upon unsealing the milling jar post-milling: the emergence of a minor fire ember, indicative of the interplay between mechanical forces and chemical reactivity within the LaH2 powder. Profound changes in the structure, composition, and shape were unraveled using advanced techniques such as X-ray diffraction (XRD), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM/EDX), and particle size distribution analysis. The resulting powder exhibited a dual-phase composition of lanthanum dihydride (LaH2, 68.1% to 71.5%) and lanthanum oxide (La2O3, 28.5% to 31.9%), reflecting a dynamic chemical equilibrium during milling. Particle size distribution analysis revealed a notable increase in average diameter to 6420 nm, accompanied by a polydispersity index (PDI) of 0.831, signifying a broadening compared to the initial LaH2 powder. The morphological evolution of the powder was elucidated through SEM imaging, showing predominantly spherical and rounded forms, indicating extensive particle agglomeration and plastic deformation during milling. Additionally, the formation of oxide layers on the powder surface, intertwined with pronounced particle agglomeration, was highlighted through EDX mapping, shedding light on the mechanical aspects of morphological evolution during milling. These findings contribute to our understanding of LaH2 behavior under extreme mechanical and chemical conditions and have implications for materials processing, hydrogen storage technologies, and broader applications in materials science and engineering.

DOI

10.55713/jmmm.v34i2.1825

First Page

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Last Page

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Recommended Citation

Pramono, Andika Widya; Herbirowo, Satrio; Imaduddin, Agung; Antoro, Iwan Dwi; Nugraha, Heri; -, Hendrik; Syampurwadi, Anung; Nufus, Ines Hayatun; Umna, Nihayatul; Diba, Silvia Farah; and Amaliyah, Fina Fitratun (2024) "The mechanochemistry of lanthanum dihydride (LaH2) with hydrogen (H2) using the ball-mill process and the effect of oxidation on the resulting products," Journal of Metals, Materials and Minerals: Vol. 34: No. 2, Article 5.
DOI: 10.55713/jmmm.v34i2.1825
Available at: https://digital.car.chula.ac.th/jmmm/vol34/iss2/5